if you get any brake fluid on them when bleeding your brakes, bye bye paint.
if you know how to paint go ahead do it just make sure to use the certain quality for rims and frames, or you can get them powder coated either way should be fine.well i had too get new rims so i was thinking of painting them, i know they should be powder coated, but trying to keep cost down , im going to prime, paint & clear coat, and im thinking of going with gloss black, what are your thaughts thanks